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Bio-Functional Cu Containing Biomaterials: a New Way to Enhance Bio-Adaption of Biomaterials

Jin Shujing , Ren Ling , Yang Ke

材料科学技术(英) doi:10.1016/j.jmst.2016.06.022

Although being an essential trace element required for human body health, Cu has long been seriously considered toxic when its amount exceeds certain limitation, which significantly limited the wide application of Cu in biomaterials. However, more and more bio-functions and benefits of Cu were found and confirmed, attracting the attention from biomaterials researchers in recent years. People have tried to immobilize Cu into biomaterials by various ways, in order to develop novel bio-functional Cu containing biomaterials with better bio-adaptions, and several different bio-functions of them have been demonstrated. This paper makes a review of the development of novel bio-functional Cu containing biomaterials, and focuses on their unique roles in enhancing bio-adaption of biomedical materials, including antibacterial performance, stimulating angiogenesis, promoting osteogenesis and inhibition of in-stent restenosis, aiming at proposing a prospective development direction for biomedical materials with better bio-adaptions.

关键词: Biomaterials , Cu , Antibacterial , Angiogenesis , Osteogenesis , In-stent restenosis

EFFECTIVE-MEDIUM THEORY OF PIEZOELECTRIC COMPOSITES

Journal of Applied Physics

Based on the developed multiple-scattering theory [C.-W. Nan and F. S. Jin, Phys. Rev. B 48, 8578 (1993)], an effective-medium theory (EMT) is proposed to treat coupled electromechanical behavior in composite media. The explicit relations for determining effective behavior of piezoelectric composites are derived. To illustrate the technique, numerical results of piezoelectric ceramic/epoxy composites for various particle shapes are presented over the whole range of concentrations. The EMT estimates are shown to be in good agreement with available experimental results. Porous piezoelectric ceramics are also discussed. The EMT predicts a similar critical behavior for heterogeneous piezoelectric materials to recent experiments.

关键词: electromechanical properties;ceramics

Interactions between non-screw lattice dislocations and coherent twin boundaries in face-centered cubic metals

Acta Materialia

In a first report [Jin ZH.. Gumbsch P, Ma E, Albe K, Lu K, Hahn H, et al. Scripta Mater 2006;54:1163], interactions between screw dislocation and coherent twin boundary (CTB) were studied via molecular dynamics simulations for three face-centered cubic (fcc) metals, Cu, Ni and Al. To complement those preliminary results, purely stress-driven interactions between 60 degrees non-screw lattice dislocation and CTB are considered in this paper. Depending on the material and the applied strain, slip has been observed to interact with the boundary in different ways. If a 60 degrees dislocation is forced by an external stress into a CTB, it dissociates into different partial dislocations gliding into the twin as well as along the twin boundary. A sessile dislocation lock may be generated at the CTB if the transited slip is incomplete. The details of the interaction are controlled by the material-dependent energy barriers for the formation of Shockley partial dislocations from the site where the lattice dislocation impinges upon the boundary. (c) 2007 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

关键词: dislocation;slip;twinning;twin grain boundary;molecular dynamics;molecular-dynamics simulation;grain-boundaries;nanocrystalline;materials;cross-slip;rate sensitivity;deformation;copper;strength;aluminum;fcc

YBCO薄膜中自旋极化准粒子的注入效应

曹春海 , 杨名 , 张世远 , 杨森祖 , 崔旭高 , 尤立星 , 吉争鸣 , 康琳 , 许伟伟

低温物理学报 doi:10.3969/j.issn.1000-3258.2003.03.002

采用Nd0.7Sr0.3MnO3/SrTiO3/YBa2Cu3O7-δ的异质结构,研究了自旋极化准粒子的注入效应.在56μm宽的YBCO膜条上成功地制备了与超导膜条同样宽度但不同长度的六个注入结区,长度L分别为80μm, 40μm, 20μm, 10μm, 5μm和2μm.80nm厚的YBCO薄膜在16K温度下Jc为2×105A/cm2.Iin=0.5mA的自旋电流注入下,随L从80μm逐渐顺次减小时,注入效率η=ΔJc/ΔJin逐渐增大.而当L≤20μm后,η不再增加,达到几乎相同的值(~6).初步分析认为这与自旋极化准粒子在超导膜内的有效自旋扩散长度有关.异质结构中YBCO薄膜的超导电性以及注入窗口的尺寸对获得大的自旋注入效率十分重要.

关键词: 注入效率 , 自旋准粒子 , 巨磁阻 , 异质材料

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